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| Author | Kalyuzhnaya, A.S.; Abakumov, A.M.; Rozova, M.G.; d' Hondt, H.; Hadermann, J.; Antipov, E.V. | ||||
| Title | Synthesis and crystal structure of the new complex oxide Ca7Mn2.14Ga5.86O17.93 | Type | A1 Journal article | ||
Year  |
2010 | Publication | Russian chemical bulletin | Abbreviated Journal | Russ Chem B+ |
| Volume | 59 | Issue | 4 | Pages | 706-711 |
| Keywords | A1 Journal article; Electron microscopy for materials research (EMAT) | ||||
| Abstract | The complex oxide Ca7Mn2.14Ga5.86O17.93 was synthesized by the solid-state reaction in a sealed evacuated quartz tube at 1000 °C. Its crystal structure was determined by electron diffraction and X-ray powder diffraction. The structure can be represented as a tetrahedral framework, viz., the polyanion [(Mn0.285Ga0.715)15O29.86]19- stabilized by the incorporated cation [Ca14GaO6]19+. The polycation consists of the GaO6 octahedra surrounded by the Ca atoms, which are arranged to form a cube capped at all places. The tetrahedral framework is partially disordered due to the presence of tetrahedra with two possible orientations in the positions (0, 0, 0) and (x, x, x) with x ≈ 0.15 and 0.17. The relationship between the Ca7Mn2.14Ga5.86O17.93 structures and related ordered phases with the symmetry F23, as well as the influence of the oxygen content on the ordering in the tetrahedral framework, are discussed. | ||||
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| Publisher | Place of Publication | Editor | |||
| Language | Wos | 000283302000006 | Publication Date | 2010-10-20 | |
| Series Editor | Series Title | Abbreviated Series Title | |||
| Series Volume | Series Issue | Edition | |||
| ISSN | 1066-5285;1573-9171; | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
| Impact Factor | 0.529 | Times cited | 1 | Open Access | |
| Notes | Approved | Most recent IF: 0.529; 2010 IF: 0.629 | |||
| Call Number | UA @ lucian @ c:irua:85675 | Serial | 3427 | ||
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