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Marchetti, A.; Beltran, V.; Nuyts, G.; Borondics, F.; De Meyer, S.; Van Bos, M.; Jaroszewicz, J.; Otten, E.; Debulpaep, M.; De Wael, K. |
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Title |
Novel optical photothermal infrared (O-PTIR) spectroscopy for the noninvasive characterization of heritage glass-metal objects |
Type |
A1 Journal article |
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Year  |
2022 |
Publication |
Science Advances |
Abbreviated Journal |
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Volume |
8 |
Issue |
9 |
Pages |
eabl6769-9 |
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Keywords |
A1 Journal article; Engineering sciences. Technology; Antwerp Electrochemical and Analytical Sciences Lab (A-Sense Lab); Antwerp X-ray Imaging and Spectroscopy (AXIS) |
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Abstract |
Optical photothermal infrared (O-PTIR) is a recently developed molecular spectroscopy technique that allows to noninvasively obtain chemical information on organic and inorganic samples at a submicrometric scale. The high spatial resolution (approximate to 450 nm), lack of sample preparation, and comparability of the spectral results to traditional Fourier transform infrared spectroscopy make it a promising candidate for the analysis of cultural heritage. In this work, the potential of O-PTIR for the noninvasive characterization of small heritage objects (few cubic centimeters) is demonstrated on a series of degraded 16th century brass and glass decorative elements. These small and challenging samples, typically encountering limitations with existing noninvasive methods such as macroscopic x-ray powder diffraction and mu Raman, were successfully characterized by O-PTIR, ultimately identifying the markers of glass-induced metal corrosion processes. The results clearly demonstrate how O-PTIR can be easily implemented in a noninvasive multianalytical strategy for the study of heritage materials, making it a fundamental tool for cultural heritage analyses. |
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Wos |
000790020300013 |
Publication Date |
2022-03-04 |
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ISSN |
2375-2548 |
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UA library record; WoS full record; WoS citing articles |
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Impact Factor |
13.6 |
Times cited |
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Open Access |
OpenAccess |
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Most recent IF: 13.6 |
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Call Number |
UA @ admin @ c:irua:188642 |
Serial |
7184 |
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Author |
Kontozova, V.; Krupińska, B.; Van Grieken, R.; Janssen, E.; Moris, H.; Aerts, D.; Watteeuw, L.; van Bos, M.; Peckstadt, A. |
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Title |
Research for preventive conservation and optimal presentation of world heritage in Museum Plantin-Moretus, Antwerp |
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P3 Proceeding |
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Year |
2011 |
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Keywords |
P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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978-989-97522-0-7 |
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no |
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Call Number |
UA @ admin @ c:irua:92095 |
Serial |
8473 |
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Author |
Janssen, E.; Kontozova-Deutsch, V.; Krupińska, B.; Moris, H.; Peckstadt, A.; van Bos, M.; Watteeuw, L.; Van Grieken, R. |
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Title |
Do gaseous pollutants and particulate matter endanger our world heritage? A study in the Museum Plantin-Moretus, Antwerp |
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P3 Proceeding |
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Year |
2010 |
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P3 Proceeding; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation) |
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Call Number |
UA @ admin @ c:irua:85520 |
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7820 |
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