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Author Navulla, A.; Tsirlin, A.A.; Abakumov, A.M.; Shpanchenko, R.V.; Zhang, H.; Dikarev, E.V. doi  openurl
  Title Fluorinated heterometallic \beta-diketonates as volatile single-source precursors for the synthesis of low-valent mixed-metal fluorides Type A1 Journal article
  Year (down) 2011 Publication Journal of the American Chemical Society Abbreviated Journal J Am Chem Soc  
  Volume 133 Issue 4 Pages 692-694  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract Hexafluoroacetylacetonates that contain lead and divalent first-row transition metals, PbM(hfac)4 (M = Ni (1), Co (2), Mn (3), Fe (4), and Zn (5)), have been synthesized. Their heterometallic structures are held together by strong Lewis acid−base interactions between metal atoms and diketonate ligands acting in chelating−bridging fashion. Compounds 1−5 are highly volatile and decompose below 350 °C. Fluorinated heterometallic β-diketonates have been used for the first time as volatile single-source precursors for the preparation of mixed-metal fluorides. Complex fluorides of composition Pb2MF6 have been obtained by decomposition of 1−5 in a two-zone furnace under low-pressure nitrogen flow. Lead−transition metal fluorides conform to orthorhombically distorted Aurivillius-type structure with layers of corner-sharing [MF6] octahedra separated by α-PbO-type (Pb2F2) blocks. Pb2NiF6 and Pb2CoF6 were found to exhibit magnetic ordering below 80 and 43 K, respectively. The ordering is antiferromagnetic, with a weak, uncompensated moment due to the canting of spins. The Pb2MF6 fluorides represent a new class of prospective magnetoelectric materials combining transition metals and lone-pair main-group cations.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Washington, D.C. Editor  
  Language Wos 000287295300015 Publication Date 2010-12-21  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0002-7863;1520-5126; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 13.858 Times cited 28 Open Access  
  Notes Approved Most recent IF: 13.858; 2011 IF: 9.907  
  Call Number UA @ lucian @ c:irua:88820 Serial 1236  
Permanent link to this record
 

 
Author Tsirlin, A.A.; Nath, R.; Abakumov, A.M.; Shpanchenko, R.V.; Geibel, C.; Rosner, H. url  doi
openurl 
  Title Frustrated square lattice with spatial anisotropy: crystal structure and magnetic properties of PbZnVO(PO4)2 Type A1 Journal article
  Year (down) 2010 Publication Physical review : B : condensed matter and materials physics Abbreviated Journal Phys Rev B  
  Volume 81 Issue 17 Pages 174424,1-174424,13  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract Crystal structure and magnetic properties of the layered vanadium phosphate PbZnVO(PO4)2 are studied using x-ray powder diffraction, magnetization and specific-heat measurements, as well as band-structure calculations. The compound resembles AA′VO(PO4)2 vanadium phosphates and fits to the extended frustrated square-lattice model with the couplings J1, J1′ between nearest neighbors and J2, J2′ between next-nearest neighbors. The temperature dependence of the magnetization yields estimates of averaged nearest-neighbor and next-nearest-neighbor couplings, J̅ 1≃−5.2 K and J̅ 2≃10.0 K, respectively. The effective frustration ratio α=J̅ 2/J̅ 1 amounts to −1.9 and suggests columnar antiferromagnetic ordering in PbZnVO(PO4)2. Specific-heat data support the estimates of J̅ 1 and J̅ 2 and indicate a likely magnetic ordering transition at 3.9 K. However, the averaged couplings underestimate the saturation field, thus pointing to the spatial anisotropy of the nearest-neighbor interactions. Band-structure calculations confirm the identification of ferromagnetic J1, J1′ and antiferromagnetic J2, J2′ in PbZnVO(PO4)2 and yield (J1′−J1)≃1.1 K in excellent agreement with the experimental value of 1.1 K, deduced from the difference between the expected and experimentally measured saturation fields. Based on the comparison of layered vanadium phosphates with different metal cations, we show that a moderate spatial anisotropy of the frustrated square lattice has minor influence on the thermodynamic properties of the model. We discuss relevant geometrical parameters, controlling the exchange interactions in these compounds and propose a strategy for further design of strongly frustrated square-lattice materials.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000278141600082 Publication Date 2010-05-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 1098-0121;1550-235X; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 3.836 Times cited 27 Open Access  
  Notes Approved Most recent IF: 3.836; 2010 IF: 3.774  
  Call Number UA @ lucian @ c:irua:83384 Serial 1294  
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Author Zhang, H.; Yang, J.-H.; Shpanchenko, R.V.; Abakumov, A.M.; Hadermann, J.; Clérac, R.; Dikarev, E.V. doi  openurl
  Title New class of single-source precursors for the synthesis of main group-transition metal oxides: heterobimetallic Pb-Mn \beta-diketonates Type A1 Journal article
  Year (down) 2009 Publication Inorganic chemistry Abbreviated Journal Inorg Chem  
  Volume 48 Issue 17 Pages 8480-8488  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract Heterometallic lead−manganese â-diketonates have been isolated in pure form by several synthetic methods that include solid-state and solution techniques. Two compounds with different Pb/Mn ratios, PbMn2(hfac)6 (1) and PbMn(hfac)4 (2) (hfac = hexafluoroacetylacetonate), can be obtained in quantitative yield by using different starting materials. Single crystal X-ray investigation revealed that the solid-state structure of 1 contains trinuclear molecules in which lead metal center is sandwiched between two [Mn(hfac)3] units, while 2 consists of infinite chains of alternating [Pb(hfac)2] and [Mn(hfac)2] fragments. The heterometallic structures are held together by strong Lewis acid−base interactions between metal atoms and diketonate ligands acting in chelating-bridging fashion. Spectroscopic investigation confirmed the retention of heterometallic structures in solutions of non-coordinating solvents as well as upon sublimation-deposition procedure. Thermal decomposition of heterometallic diketonates has been systematically investigated in a wide range of temperatures and annealing times. For the first time, it has been shown that thermal decomposition of heterometallic diketonates results in mixed-metal oxides, while both the structure of precursors and the thermolysis conditions have a significant influence on the nature of the resulting oxides. Five different Pb−Mn oxides have been detected by X-ray powder diffraction when studying the decomposition of 1 and 2 in the temperature range 500−800 °C. The phase that has been previously reported as Pb0.43MnO2.18 was synthesized in the pure form by decomposition of 1, and crystallographically characterized. The orthorhombic unit cell parameters of this oxide, obtained by electron diffraction technique, have been subsequently refined using X-ray powder diffraction data. Besides that, a previously unknown lead−manganese oxide has been obtained at low temperature decomposition and short annealing times. The parameters of its monoclinically distorted unit cell have been determined. The EDX analysis revealed that this compound has a Pb/Mn ratio close to 1:4 and contains no appreciable amount of fluorine.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Easton, Pa Editor  
  Language Wos 000269313500056 Publication Date 2009-08-04  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0020-1669;1520-510X; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 4.857 Times cited 28 Open Access  
  Notes Approved Most recent IF: 4.857; 2009 IF: 4.657  
  Call Number UA @ lucian @ c:irua:78486 Serial 2308  
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Author Abakumov, A.M.; Hadermann, J.; Tsirlin, A.A.; Tan, H.; Verbeeck, J.; Zhang, H.; Dikarev, E.V.; Shpanchenko, R.V.; Antipov, E.V. doi  openurl
  Title Original close-packed structure and magnetic properties of the Pb4Mn9O20 manganite Type A1 Journal article
  Year (down) 2009 Publication Journal of solid state chemistry Abbreviated Journal J Solid State Chem  
  Volume 182 Issue 8 Pages 2231-2238  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract The crystal structure of the Pb4Mn9O20 compound (previously known as Pb0.43MnO2.18) was solved from powder X-ray diffraction, electron diffraction, and high resolution electron microscopy data (S.G. Pnma, a=13.8888(2) Å, b=11.2665(2) Å, c=9.9867(1) Å, RI=0.016, RP=0.047). The structure is based on a 6H (cch)2 close packing of pure oxygen h-type (O16) layers alternating with mixed c-type (Pb4O12) layers. The Mn atoms occupy octahedral interstices formed by the oxygen atoms of the close-packed layers. The MnO6 octahedra share edges within the layers, whereas the octahedra in neighboring layers are linked through corner sharing. The relationship with the closely related Pb3Mn7O15 structure is discussed. Magnetization measurements reveal a peculiar magnetic behavior with a phase transition at 52 K, a small net magnetization below the transition temperature, and a tendency towards spin freezing.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication London Editor  
  Language Wos 000269066400035 Publication Date 2009-06-12  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0022-4596; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 2.299 Times cited 5 Open Access  
  Notes The authors are grateful to Christoph Geibel for the help in magnetization measurements. A.Ts. acknowledges MPI CKS for hospitality and financial support during the stay. E.D. thanks the National Science Foundation (CHE-0718900) for financial support. This work was supported by the Russian Foundation of Basic Research (RFBR Grants 07-03-00664-a, 06-03-90168-a and 07-03-00890-a). The authors acknowledge financial support from the European Union under the Framework 6 program under a contract for an Integrated Infrastructure Initiative. Reference 026019 ESTEEM. Approved Most recent IF: 2.299; 2009 IF: 2.340  
  Call Number UA @ lucian @ c:irua:78935UA @ admin @ c:irua:78935 Serial 2529  
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Author Shpanchenko, R.V.; Tsirlin, A.A.; Hadermann, J.; Antipov, E.V. doi  openurl
  Title Synthesis and crystal structure of new titanyl phosphate Sr2TiO(PO4)2 Type A1 Journal article
  Year (down) 2008 Publication Russian chemical bulletin Abbreviated Journal Russ Chem B+  
  Volume 57 Issue 3 Pages 552-556  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract New strontium titanyl phosphate Sr2TiO(PO4)2 (1) was synthesized and characterized by X-ray powder diffraction, electron diffraction, high-resolution electron microscopy, and band structure calculations. Titanyl phosphate 1 is isostructural with vanadyl phosphate Sr2VO(PO4)2 and has a layered structure. The titanium atoms are shifted from the centers of the TiO6 octahedra and form short (1.74 Å) titanyl bonds. The structure of 1 is an unusual example of the disordered orientation of the chains formed by TiO6 octahedra in complex titanium phosphates.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000263566900015 Publication Date 2009-03-06  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 1066-5285;1573-9171; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 0.529 Times cited 2 Open Access  
  Notes Approved Most recent IF: 0.529; 2008 IF: 0.469  
  Call Number UA @ lucian @ c:irua:73712 Serial 3423  
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Author Shpanchenko, R.V.; Tsirlin, A.A.; Kondakova, E.S.; Antipov, E.V.; Bougerol, C.; Hadermann, J.; Van Tendeloo, G.; Sakurai, H.; Takayama-Muromachi, E. doi  openurl
  Title New germanates RCrGeO5 (R=NdEr, Y): synthesis, structure, and properties Type A1 Journal article
  Year (down) 2008 Publication Journal of solid state chemistry Abbreviated Journal J Solid State Chem  
  Volume 181 Issue 9 Pages 2433-2441  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract The new complex germanates RCrGeO5 (R=NdEr, Y) have been synthesized and investigated by means of X-ray powder diffraction, electron microscopy, magnetic susceptibility and specific heat measurements. All the compounds are isostructural and crystallize in the orthorhombic symmetry, space group Pbam, and Z=4. The crystal structure of RCrGeO5, as refined using X-ray powder diffraction data, includes infinite chains built by edge-sharing Cr+3O6 octahedra with two alternating Cr−Cr distances. The chains are combined into a three-dimensional framework by Ge2O8 groups consisting of two edge-linked square pyramids oriented in opposite directions. The resulting framework contains pentagonal channels where rare-earth elements are located. Thus, RCrGeO5 germanates present new examples of RMn2O5-type compounds and show ordering of Cr+3 and Ge+4 cations. Electron diffraction as well as high-resolution electron microscopy confirm the structure solution. Magnetic susceptibility data for R=Nd, Sm, and Eu are qualitatively consistent with the presence of isolated 3d (antiferromagnetically coupled Cr+3 cations) and 4f (R+3) spin subsystems in the RCrGeO5 compounds. NdCrGeO5 undergoes long-range magnetic ordering at 2.6 K, while SmCrGeO5 and EuCrGeO5 do not show any phase transitions down to 2 K.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication London Editor  
  Language Wos 000259415800047 Publication Date 2008-06-06  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0022-4596; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 2.299 Times cited 6 Open Access  
  Notes Approved Most recent IF: 2.299; 2008 IF: 1.910  
  Call Number UA @ lucian @ c:irua:72948 Serial 2314  
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Author Tsirlin, A.A.; Shpanchenko, R.V.; Antipov, E.V.; Bougerol, C.; Hadermann, J.; Van Tendeloo, G.; Schnelle, W.; Rosner, H. doi  openurl
  Title Spin ladder compound Pb0.55Cd0.45V2O5: synthesis and investigation Type A1 Journal article
  Year (down) 2007 Publication Physical review : B : condensed matter and materials physics Abbreviated Journal Phys Rev B  
  Volume 76 Issue 10 Pages 104429,1-7  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Lancaster, Pa Editor  
  Language Wos 000249786300074 Publication Date 2007-09-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 1098-0121;1550-235X; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 3.836 Times cited 1 Open Access  
  Notes Approved Most recent IF: 3.836; 2007 IF: 3.172  
  Call Number UA @ lucian @ c:irua:65594 Serial 3091  
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Author Shpanchenko, R.V.; Panin, R.V.; Hadermann, J.; Bougerol, C.; Takayama-Muromachi, E.; Antipov, E.V. pdf  doi
openurl 
  Title Synthesis and structure investigation of the Pb3V(PO4)3 eulytite Type A1 Journal article
  Year (down) 2005 Publication Journal of solid state chemistry Abbreviated Journal J Solid State Chem  
  Volume 178 Issue 12 Pages 3715-3721  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication London Editor  
  Language Wos 000234442100016 Publication Date 2005-11-03  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0022-4596; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 2.299 Times cited 17 Open Access  
  Notes Rfbr; Icdd; Iap V-1 Approved Most recent IF: 2.299; 2005 IF: 1.725  
  Call Number UA @ lucian @ c:irua:55029 Serial 3441  
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Author Shpanchenko, R.V.; Lapshina, O.A.; Antipov, E.V.; Hadermann, J.; Kaul, E.E.; Geibel, C. pdf  doi
openurl 
  Title New lead vanadium phosphate with langbeinite-type structure: Pb1.5V2(PO4)3 Type A1 Journal article
  Year (down) 2005 Publication Materials research bulletin Abbreviated Journal Mater Res Bull  
  Volume 40 Issue 9 Pages 1569-1576  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication New York, N.Y. Editor  
  Language Wos 000231208100018 Publication Date 2005-06-01  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0025-5408; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 2.446 Times cited 14 Open Access  
  Notes Approved Most recent IF: 2.446; 2005 IF: 1.380  
  Call Number UA @ lucian @ c:irua:55031 Serial 2320  
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Author Tsirlin, A.A.; Chernaya, V.V.; Shpanchenko, R.V.; Antipov, E.V.; Hadermann, J. pdf  doi
openurl 
  Title Crystal structure and properties of the new complex vanadium oxide K2SrV3O9 Type A1 Journal article
  Year (down) 2005 Publication Materials research bulletin Abbreviated Journal Mater Res Bull  
  Volume 40 Issue 5 Pages 800-809  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication New York, N.Y. Editor  
  Language Wos 000229376500010 Publication Date 2005-03-01  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0025-5408; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 2.446 Times cited 9 Open Access  
  Notes Approved Most recent IF: 2.446; 2005 IF: 1.380  
  Call Number UA @ lucian @ c:irua:52373 Serial 564  
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Author Kopnin, E.M.; Belik, A.A.; Shpanchenko, R.V.; Antipov, E.V.; Izumi, F.; Takayama-Muromachi, E.; Hadermann, J. pdf  doi
openurl 
  Title Synthesis, crystal structure, and magnetic properties of new layered hexagonal perovskite Ba8Ta4Ru8/3Co2/3O24 Type A1 Journal article
  Year (down) 2004 Publication Journal of solid state chemistry Abbreviated Journal J Solid State Chem  
  Volume 177 Issue Pages 3499-3504  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication London Editor  
  Language Wos 000224465500035 Publication Date 2004-08-13  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0022-4596; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 2.299 Times cited 1 Open Access  
  Notes reprint; IUAP V-1 Approved Most recent IF: 2.299; 2004 IF: 1.815  
  Call Number UA @ lucian @ c:irua:49462 Serial 3448  
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Author Chernaya, V.V.; Tsirlin, A.A.; Shpanchenko, R.V.; Antipov, E.V.; Gippius, A.A.; Morozova, E.N.; Dyakov, V.; Hadermann, J.; Kaul, E.E.; Geibel, C. pdf  doi
openurl 
  Title Crystal structure and properties of the new vanadyl(IV)phosphates Na2MVO(PO4)2 M=Ca and Sr Type A1 Journal article
  Year (down) 2004 Publication Journal of solid state chemistry Abbreviated Journal J Solid State Chem  
  Volume 177 Issue Pages 2875-2880  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication London Editor  
  Language Wos 000223145500033 Publication Date 2004-08-04  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0022-4596; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 2.299 Times cited 6 Open Access  
  Notes Approved Most recent IF: 2.299; 2004 IF: 1.815  
  Call Number UA @ lucian @ c:irua:47317 Serial 565  
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Author Panin, R.V.; Shpanchenko, R.V.; Mironov, A.V.; Velikodny, Y.A.; Antipov, E.V.; Hadermann, J.; Tarnopolsky, V.A.; Yaroslavtsev, A.B.; Kaul, E.E.; Geibel, C. pdf  doi
openurl 
  Title Crystal structure, polymorphism, and properties of the new vanadyl phosphate Na4VO(PO4)2 Type A1 Journal article
  Year (down) 2004 Publication Chemistry of materials Abbreviated Journal Chem Mater  
  Volume 16 Issue Pages 1048-1055  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Washington, D.C. Editor  
  Language Wos 000220304100014 Publication Date 2004-03-16  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0897-4756;1520-5002; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 9.466 Times cited 11 Open Access  
  Notes Approved Most recent IF: 9.466; 2004 IF: 4.103  
  Call Number UA @ lucian @ c:irua:43873 Serial 577  
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Author Shpanchenko, R.V.; Chernaya, V.V.; Antipov, E.V.; Hadermann, J.; Kaul, E.E.; Geibel, C. doi  openurl
  Title Synthesis, structure and magnetic properties of the new mixed-valence vanadate Na2SrV3O9 Type A1 Journal article
  Year (down) 2003 Publication Journal of solid state chemistry Abbreviated Journal J Solid State Chem  
  Volume 173 Issue Pages 244-250  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication London Editor  
  Language Wos 000183489700032 Publication Date 2003-03-15  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0022-4596; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 2.299 Times cited 5 Open Access  
  Notes Approved Most recent IF: 2.299; 2003 IF: 1.413  
  Call Number UA @ lucian @ c:irua:42055 Serial 3461  
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Author Shpanchenko, R.V.; Chyornaya, V.V.; Abakumov, A.M.; Antipov, E.V.; Hadermann, J.; Van Tendeloo, G.; Kaul, E.; Geibel, C.; Sheptyakov, D.; Balagurov, A.M. doi  openurl
  Title Crystal structure and magnetic properties of novel reduced V(IV)-based oxide Pb2V5O12 Type A1 Journal article
  Year (down) 2001 Publication Zeitschrift für anorganische und allgemeine Chemie Abbreviated Journal Z Anorg Allg Chem  
  Volume 627 Issue Pages 2143-2150  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Leipzig Editor  
  Language Wos 000171339000023 Publication Date 2002-08-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0044-2313;1521-3749; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 1.144 Times cited 4 Open Access  
  Notes Approved Most recent IF: 1.144; 2001 IF: 1.165  
  Call Number UA @ lucian @ c:irua:36048 Serial 560  
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Author Oleynikov, P.N.; Shpanchenko, R.V.; Rozova, M.G.; Abakumov, A.M.; Antipov, E.V.; Hadermann, J.; Lebedev, O.I.; Van Tendeloo, G. openurl 
  Title Synthesis and structure of fluorinated RBa2Cu2O6+. (R=Dy, Ho and Tm) phases Type A1 Journal article
  Year (down) 2001 Publication Russian journal of inorganic chemistry Abbreviated Journal Russ J Inorg Chem+  
  Volume 46 Issue 2 Pages 153-158  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication London Editor  
  Language Wos Publication Date 0000-00-00  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0036-0236 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 0.787 Times cited Open Access  
  Notes Approved Most recent IF: 0.787; 2001 IF: NA  
  Call Number UA @ lucian @ c:irua:36045 Serial 3443  
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Author Hadermann, J.; Abakumov, A.M.; Lebedev, O.I.; Van Tendeloo, G.; Rozova, M.G.; Shpanchenko, R.V.; Pavljuk, B.P.; Kopnin, E.M.; Antipov, E.V. pdf  doi
openurl 
  Title Structural transformations in the fluorinated T* phase Type A1 Journal article
  Year (down) 1999 Publication Journal of solid state chemistry Abbreviated Journal J Solid State Chem  
  Volume 147 Issue Pages 647-656  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication London Editor  
  Language Wos 000083652600028 Publication Date 2002-10-07  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0022-4596; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 2.299 Times cited 8 Open Access  
  Notes Approved Most recent IF: 2.299; 1999 IF: 1.547  
  Call Number UA @ lucian @ c:irua:29279 Serial 3266  
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Author Abakumov, A.M.; Hadermann, J.; Van Tendeloo, G.; Shpanchenko, R.V.; Oleinikov, P.N.; Antipov, E.V. pdf  doi
openurl 
  Title Anion ordering in fluorinated La2CuO4 Type A1 Journal article
  Year (down) 1999 Publication Journal of solid state chemistry Abbreviated Journal J Solid State Chem  
  Volume 142 Issue Pages 311-322  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication London Editor  
  Language Wos 000078597400024 Publication Date 2002-10-07  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0022-4596; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 2.299 Times cited 20 Open Access  
  Notes Approved Most recent IF: 2.299; 1999 IF: 1.547  
  Call Number UA @ lucian @ c:irua:29277 Serial 121  
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Author Abakumov, A.M.; Shpanchenko, R.V.; Lebedev, O.I.; Van Tendeloo, G.; Amelinckx, S.; Antipov, E.V. doi  openurl
  Title The phase transition and crystal structures of Ba3RM2O7.5 complex oxides (R=rare-earth elements, M = Al,Ga) Type A1 Journal article
  Year (down) 1999 Publication Acta crystallographica: section A: foundations of crystallography Abbreviated Journal Acta Crystallogr A  
  Volume 55 Issue Pages 828-839  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Copenhagen Editor  
  Language Wos 000082727000006 Publication Date 2002-07-27  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0108-7673; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 5.725 Times cited 7 Open Access  
  Notes Approved Most recent IF: 5.725; 1999 IF: 1.601  
  Call Number UA @ lucian @ c:irua:29716 Serial 2591  
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Author Van Tendeloo, G.; Lebedev, O.I.; Verbist, K.; Abakumov, A.M.; Shpanchenko, R.V.; Antipov, E.V.; Blank, D.H.A. openurl 
  Title The local structure of YBCO based materials by TEM Type H1 Book chapter
  Year (down) 1999 Publication Abbreviated Journal  
  Volume Issue Pages 11-19  
  Keywords H1 Book chapter; Electron microscopy for materials research (EMAT)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Kluwer Academic Place of Publication Dordrecht Editor  
  Language Wos 000079308200002 Publication Date 0000-00-00  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN ISBN Additional Links UA library record; WoS full record;  
  Impact Factor Times cited Open Access  
  Notes Approved Most recent IF: NA  
  Call Number UA @ lucian @ c:irua:29709 Serial 1833  
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Author Hadermann, J.; Abakumov, A.M.; Van Tendeloo, G.; Shpanchenko, R.V.; Oleinikov, P.N.; Antipov, E.V. openurl 
  Title Anion ordering in fluorinated La2CuO4 Type H1 Book chapter
  Year (down) 1999 Publication Abbreviated Journal  
  Volume Issue Pages 133-138  
  Keywords H1 Book chapter; Electron microscopy for materials research (EMAT)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication s.l. Editor  
  Language Wos 000079308200022 Publication Date 0000-00-00  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN ISBN Additional Links UA library record; WoS full record;  
  Impact Factor Times cited Open Access  
  Notes Approved Most recent IF: NA  
  Call Number UA @ lucian @ c:irua:29278 Serial 122  
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Author Abakumov, A.M.; Shpanchenko, R.V.; Antipov, E.V.; Kopnin, E.M.; Capponi, J.J.; Marezio, M.; Lebedev, O.I.; Van Tendeloo, G.; Amelinckx, S. pdf  doi
openurl 
  Title Synthesis and structural study of Pb2Re2O7-x pyrochlores Type A1 Journal article
  Year (down) 1998 Publication Journal of solid state chemistry Abbreviated Journal J Solid State Chem  
  Volume 138 Issue Pages 220-225  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication London Editor  
  Language Wos 000075369600005 Publication Date 2002-10-07  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0022-4596; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 2.299 Times cited 5 Open Access  
  Notes Approved Most recent IF: 2.299; 1998 IF: 1.432  
  Call Number UA @ lucian @ c:irua:25665 Serial 3439  
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Author Abakumov, A.M.; Shpanchenko, R.V.; Antipov, E.V.; Lebedev, O.I.; Van Tendeloo, G.; Amelinckx, S. pdf  doi
openurl 
  Title Synthesis and structural study of hexagonal pervoskites in the Ba5>Ta4O15-MZrO3 (M=Ba, Sr) system Type A1 Journal article
  Year (down) 1998 Publication Journal of solid state chemistry Abbreviated Journal J Solid State Chem  
  Volume 141 Issue Pages 492-499  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication London Editor  
  Language Wos 000077837100024 Publication Date 2002-09-18  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0022-4596; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 2.299 Times cited 17 Open Access  
  Notes Approved Most recent IF: 2.299; 1998 IF: 1.432  
  Call Number UA @ lucian @ c:irua:25666 Serial 3438  
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Author Bramnik, K.G.; Abakumov, A.M.; Shpanchenko, R.V.; Antipov, E.V.; Van Tendeloo, G. doi  openurl
  Title Synthesis and structure of Ln4Re6-xO19 (Ln=Ce, Pr, Nd) complex oxides Type A1 Journal article
  Year (down) 1998 Publication Journal of alloys and compounds Abbreviated Journal J Alloy Compd  
  Volume 278 Issue Pages 98-102  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Amsterdam Editor  
  Language Wos 000075799200020 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0925-8388; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 3.133 Times cited 8 Open Access  
  Notes Approved Most recent IF: 3.133; 1998 IF: 0.880  
  Call Number UA @ lucian @ c:irua:25677 Serial 3444  
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Author Abakumov, A.; Rozova, M.; Shpanchenko, R.; Kovba, M.; Putilin, S.; Antipov, E.; Lebedev, O.; Van Tendeloo, G.; Kopnin, E.; Karpinski, J. doi  openurl
  Title Effects of fluorination on the structure and superconducting properties of Y2Ba4Cu7O14+ phases Type A1 Journal article
  Year (down) 1998 Publication Physica: C : superconductivity Abbreviated Journal Physica C  
  Volume 301 Issue Pages 155-164  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Amsterdam Editor  
  Language Wos 000074516500005 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0921-4534; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 1.404 Times cited 9 Open Access  
  Notes Approved Most recent IF: 1.404; 1998 IF: 1.086  
  Call Number UA @ lucian @ c:irua:25663 Serial 862  
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Author Lebedev, O.I.; Van Tendeloo, G.; Abakumov, A.M.; Shpanchenko, R.V.; Rozova, M.G.; Antipov, E.V. openurl 
  Title Structure of Y123 and Y247 fluorinated phases by HREM Type A1 Journal article
  Year (down) 1998 Publication Electron microscopy: vol. 3 Abbreviated Journal  
  Volume Issue Pages 297-298  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Wos 000077020300142 Publication Date 0000-00-00  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN ISBN Additional Links UA library record; WoS full record;  
  Impact Factor Times cited Open Access  
  Notes Approved Most recent IF: NA  
  Call Number UA @ lucian @ c:irua:25673 Serial 3315  
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Author Antipov, E.V.; Putilin, S.N.; Shpanchenko, R.V.; Alyoshin, V.A.; Rozova, M.G.; Abakumov, A.M.; Mikhailova, D.A.; Balagurov, A.M.; Lebedev, O.; Van Tendeloo, G. doi  openurl
  Title Structural features, oxygen and fluorine doping in Cu-based superconductors Type A1 Journal article
  Year (down) 1997 Publication Physica: C : superconductivity T2 – International Conference on Materials and Mechanisms of, Superconductivity – High Temperature Superconductors V, Feb. 28-Mar. 04, 1997, Beijing, Peoples R. China Abbreviated Journal Physica C  
  Volume 282 Issue Part 1 Pages 61-64  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract The variation of structures and superconducting properties by changing extra oxygen or fluorine atoms concentration in Hg-based Cu mixed oxides and YBa2Cu3O6+delta was studied. The data obtained by NPD study of Hg-1201 can be considered as an evidence of the conventional oxygen doping mechanism with 2 delta holes per (CuO2) layer. The extra oxygen atom was found to be located in the middle of the Hg mesh only. Different formal charges of oxygen and fluorine inserted into reduced 123 structure results in its distinct variations. The fluorine incorporation into strongly reduced YBa2Cu3O6+delta causes a significant structural rearrangement and the formation of a new compound with a composition close to YBa2Cu3O6F2 (tetragonal alpha = 3.87 Angstrom and c approximate to 13 Angstrom), which structure was deduced from the combined results of X-ray diffraction, electron diffraction and high resolution electron microscopy. Fluorination treatment by XeF2 of nonsuperconducting 123 samples causes an appearance of bulk superconductivity with T-c up to 94K.  
  Address  
  Corporate Author Thesis  
  Publisher Elsevier Science Place of Publication Amsterdam Editor  
  Language Wos A1997XZ90400019 Publication Date 2002-07-25  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0921-4534; ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 1.404 Times cited 10 Open Access  
  Notes Approved Most recent IF: 1.404; 1997 IF: 2.199  
  Call Number UA @ lucian @ c:irua:95866 Serial 3237  
Permanent link to this record
 

 
Author Van Tendeloo, G.; Lebedev, O.I.; Shpanchenko, R.V.; Antipov, E.V. openurl 
  Title Structure determination of YBCO fluorinated phases by HREM Type A1 Journal article
  Year (down) 1997 Publication Journal of electron microscopy Abbreviated Journal Microscopy-Jpn  
  Volume 1 Issue Pages 23-31  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Tokyo Editor  
  Language Wos Publication Date 0000-00-00  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0022-0744; 1477-9986 ISBN Additional Links UA library record  
  Impact Factor 0.9 Times cited Open Access  
  Notes Approved Most recent IF: NA  
  Call Number UA @ lucian @ c:irua:21418 Serial 3301  
Permanent link to this record
 

 
Author Shpanchenko, R.V.; Rozova, M.G.; Abakumov, A.M.; Ardashnikova, E.I.; Kovba, M.L.; Putilin, S.N.; Antipov, E.V.; Lebedev, O.I.; Van Tendeloo, G. openurl 
  Title Inducing superconductivity and structural transformations by fluorination of reduced YBCO Type A1 Journal article
  Year (down) 1997 Publication Physica: C : superconductivity Abbreviated Journal Physica C  
  Volume 280 Issue Pages 272-280  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Amsterdam Editor  
  Language Wos A1997XX21600005 Publication Date 0000-00-00  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0921-4534 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 1.404 Times cited 35 Open Access  
  Notes Approved Most recent IF: 1.404; 1997 IF: 2.199  
  Call Number UA @ lucian @ c:irua:21449 Serial 1604  
Permanent link to this record
 

 
Author Abakumov, A.M.; Shpanchenko, R.V.; Antipov, E.V.; Lebedev, O.I.; Van Tendeloo, G. openurl 
  Title The crystal structure of Ca3ReO6 Type A1 Journal article
  Year (down) 1997 Publication Journal of solid state chemistry Abbreviated Journal J Solid State Chem  
  Volume 131 Issue Pages 305-309  
  Keywords A1 Journal article; Electron microscopy for materials research (EMAT)  
  Abstract  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication London Editor  
  Language Wos A1997XQ33000014 Publication Date 0000-00-00  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0022-4596 ISBN Additional Links UA library record; WoS full record; WoS citing articles  
  Impact Factor 2.299 Times cited 10 Open Access  
  Notes Approved Most recent IF: 2.299; 1997 IF: 1.486  
  Call Number UA @ lucian @ c:irua:21442 Serial 571  
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