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Author |
Gropp, C.; Canossa, S.; Wuttke, S.; Gándara, F.; Li, Q.; Gagliardi, L.; Yaghi, O.M. |
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Title |
Standard Practices of Reticular Chemistry |
Type |
A1 Journal article |
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Year |
2020 |
Publication |
Acs Central Science |
Abbreviated Journal |
Acs Central Sci |
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Volume |
6 |
Issue |
8 |
Pages |
1255-1273 |
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Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
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Abstract |
Since 1995 when the first of metal−organic frameworks was crystallized with the strong bond approach, where metal ions are joined by charged organic linkers exemplified by carboxylates, followed by proof of their porosity in 1998 and ultrahigh porosity in 1999, a revolution in the development of their chemistry has ensued. This is being reinforced by the discovery of two- and three-dimensional covalent organic frameworks in 2005 and 2007. Currently, the chemistry of such porous, crystalline frameworks is collectively referred to as reticular chemistry, which is being practiced in over 100 countries. The involvement of researchers from various backgrounds and fields, and the vast scope of this chemistry and its societal applications, necessitate articulating the “Standard Practices of Reticular Chemistry”. |
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Wos |
000566668400005 |
Publication Date |
2020-08-26 |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
2374-7943 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
18.2 |
Times cited |
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Open Access |
OpenAccess |
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Notes |
S.C. acknowledges the Research Foundation Flanders (FWO) for supporting his research (Project 12ZV120N). |
Approved |
Most recent IF: 18.2; 2020 IF: 7.481 |
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Call Number |
EMAT @ emat @c:irua:172057 |
Serial |
6423 |
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Author |
Ejsmont, A.; Andreo, J.; Lanza, A.; Galarda, A.; Macreadie, L.; Wuttke, S.; Canossa, S.; Ploetz, E.; Goscianska, J. |
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Title |
Applications of reticular diversity in metal-organic frameworks : an ever-evolving state of the art |
Type |
A1 Journal article |
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Year |
2021 |
Publication |
Coordination Chemistry Reviews |
Abbreviated Journal |
Coordin Chem Rev |
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Volume |
430 |
Issue |
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Pages |
213655 |
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Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
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Abstract |
Metal-organic frameworks (MOFs) are exciting materials due to their extensive applicability in a multitude of modern technological fields. Their most prominent characteristic and primary origin of their widespread success is the exceptional variety of their structures, which we termed 'reticular diversity'. Naturally, the ever-emerging applications of MOFs made it increasingly common that researchers from various areas delve into reticular chemistry to overcome their scientific challenges. This confers a crucial role to comprehensive overviews capable of providing newcomers with the knowledge of the state of the art, as well as with the key physics and chemistry considerations needed to design MOFs for a specific application. In this review, we commit to this purpose by outlining the fundamental understanding needed to carefully navigate MOFs' reticular diversity in their main fields of application, namely hostguest chemistry, chemical sensing, electronics, photophysics, and catalysis. Such knowledge and a meticulous, open-minded approach to the design of MOFs paves the way for their most innovative and successful applications, and for the global advancement of the research areas they are employed in. (C) 2020 Elsevier B.V. All rights reserved. |
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Wos |
000615299000008 |
Publication Date |
2020-12-13 |
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Edition |
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ISSN |
0010-8545 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
13.324 |
Times cited |
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Open Access |
OpenAccess |
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Notes |
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Approved |
Most recent IF: 13.324 |
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Call Number |
UA @ admin @ c:irua:176731 |
Serial |
6715 |
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Author |
Freund, R.; Canossa, S.; Cohen, S.M.; Yan, W.; Deng, H.; Guillerm, V.; Eddaoudi, M.; Madden, D.G.; Fairen-Jimenez, D.; Lyu, H.; Macreadie, L.K.; Ji, Z.; Zhang, Y.; Wang, B.; Haase, F.; Wöll, C.; Zaremba, O.; Andreo, J.; Wuttke, S.; Diercks, C.S. |
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Title |
25 years of Reticular Chemistry |
Type |
A1 Journal article |
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Year |
2021 |
Publication |
Angewandte Chemie-International Edition |
Abbreviated Journal |
Angew Chem Int Edit |
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Volume |
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Issue |
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Pages |
anie.202101644 |
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Keywords |
A1 Journal article; Electron microscopy for materials research (EMAT) |
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Abstract |
At its core, reticular chemistry has translated the precision and expertise of organic and inorganic synthesis to the solid state. While initial excitement over metal‐organic frameworks (MOFs) and covalent organic frameworks (COFs) was undoubtedly fueled by their unprecedented porosity and surface areas, the most profound scientific innovation of the field has been the elaboration of design strategies for the synthesis of extended crystalline solids through strong directional bonds. In this contribution we highlight the different classes of reticular materials that have been developed, how these frameworks can be functionalized and how complexity can be introduced into their backbones. Finally, we show how the structural control over these materials is being extended from the molecular scale to their crystal morphology and shape on the nanoscale, all the way to their shaping on the bulk scale. |
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Wos |
000672037800001 |
Publication Date |
2021-03-29 |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
1433-7851 |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
11.994 |
Times cited |
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Open Access |
OpenAccess |
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Notes |
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Approved |
Most recent IF: 11.994 |
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Call Number |
EMAT @ emat @c:irua:177778 |
Serial |
6743 |
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Author |
Canossa, S.; Wuttke, S. |
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Title |
Functionalization chemistry of porous materials |
Type |
Editorial |
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Year |
2020 |
Publication |
Advanced Functional Materials |
Abbreviated Journal |
Adv Funct Mater |
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Volume |
30 |
Issue |
41 |
Pages |
2003875 |
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Keywords |
Editorial; Engineering sciences. Technology; Electron microscopy for materials research (EMAT) |
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Wos |
000580514700004 |
Publication Date |
2020-10-08 |
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Abbreviated Series Title |
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Series Volume |
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Series Issue |
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Edition |
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ISSN |
1616-301x |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
19 |
Times cited |
1 |
Open Access |
OpenAccess |
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Notes |
; ; |
Approved |
Most recent IF: 19; 2020 IF: 12.124 |
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Call Number |
UA @ admin @ c:irua:173614 |
Serial |
6524 |
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Author |
Ji, Z.; Wang, H.; Canossa, S.; Wuttke, S.; Yaghi, O.M. |
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Title |
Pore Chemistry of Metal–Organic Frameworks |
Type |
A1 Journal article |
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Year |
2020 |
Publication |
Advanced Functional Materials |
Abbreviated Journal |
Adv Funct Mater |
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Volume |
30 |
Issue |
41 |
Pages |
2000238 |
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Keywords |
A1 Journal article; Engineering sciences. Technology; Electron microscopy for materials research (EMAT) |
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Abstract |
The pores in metal–organic frameworks (MOFs) can be functionalized by placing chemical entities along the backbone and within the backbone. This chemistry is enabled by the architectural, thermal, and chemical robustness of the frameworks and the ability to characterize them by many diffraction and spectroscopic techniques. The pore chemistry of MOFs is articulated in terms of site isolation, coupling, and cooperation and relate that to their functions in guest recognition, catalysis, ion and electron transport, energy transfer, pore‐dynamic modulation, and interface construction. It is envisioned that the ultimate control of pore chemistry requires arranging functionalities into defined sequences and developing techniques for reading and writing such sequences within the pores. |
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Wos |
000532830900001 |
Publication Date |
2020-05-16 |
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Edition |
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ISSN |
1616-301X |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
19 |
Times cited |
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Open Access |
OpenAccess |
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Notes |
(Not present) |
Approved |
Most recent IF: 19; 2020 IF: 12.124 |
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Call Number |
EMAT @ emat @c:irua:169485 |
Serial |
6422 |
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Author |
Canossa, S.; Ji, Z.; Wuttke, S. |
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Title |
Circumventing Wear and Tear of Adaptive Porous Materials |
Type |
A1 Journal article |
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Year |
2020 |
Publication |
Advanced Functional Materials |
Abbreviated Journal |
Adv Funct Mater |
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Volume |
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Issue |
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Pages |
1908547 |
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Keywords |
A1 Journal article; Engineering sciences. Technology; Electron microscopy for materials research (EMAT) |
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Abstract |
The assessment of the architectural stability of molecular porous materials is not yet a common practice, but critical to their understanding and development. The conformational adaptation of porous materials to guest binding and other chemical dynamics poses a risk of architectural damage, leading to performance deterioration during their prolonged usage. The deformation of the framework backbone and the disconnection of building units are driven by chemical, mechanical, and thermal perturbations, and can be quantitatively described by the term connection completeness. Analytical means that can be used to measure this parameter are presented in order to provide a standard, practical protocol for evaluating architectural damage made to framework materials. Preventive and remedial strategies are proposed for enhancing the architectural integrity of frameworks without compromising their functional mechanisms, paving the way to the design of robust yet adaptive materials. In this way, the discussion on architectural stability is initiated, and readers are encouraged to carefully characterize molecular porous materials for a better understanding of their structure-property relationship. |
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Wos |
000511238300001 |
Publication Date |
2020-02-06 |
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Series Issue |
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Edition |
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ISSN |
1616-301X |
ISBN |
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Additional Links |
UA library record; WoS full record; WoS citing articles |
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Impact Factor |
19 |
Times cited |
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Open Access |
OpenAccess |
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Notes |
Fonds Wetenschappelijk Onderzoek, 12ZV120N ; |
Approved |
Most recent IF: 19; 2020 IF: 12.124 |
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Call Number |
EMAT @ emat @c:irua:166505 |
Serial |
6387 |
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