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| Author | Lybaert, J.; Trashin, S.; Maes, B.U.W.; De Wael, K.; Abbaspour Tehrani, K. | ||||
| Title | Cooperative electrocatalytic and chemoselective alcohol oxidation by Shvo's catalyst | Type | A1 Journal article | ||
| Year | 2017 | Publication | Advanced synthesis and catalysis | Abbreviated Journal | Adv Synth Catal |
| Volume | 359 | Issue | 6 | Pages | 919-925 |
| Keywords | A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Organic synthesis (ORSY) | ||||
| Abstract | A new electrocatalytic conversion of alcohols to ketones and aldehydes was developed based on an electrochemical study of Shvos complex. The oxidation of secondary alcohols was efficiently performed under mild conditions using a catalytic amount of Shvos catalyst, in combination with a sub-stoichiometric amount of 2,6-dimethoxy-1,4- benzoquinone in N,N-dimethylformamide at 80 8C. The hydroquinone thus formed is continuously reoxidized with the aid of an electrochemical device. Excellent yields for different ketones, aromatic as well as aliphatic and a,b-unsaturated ketones, are obtained. In addition, chemoselectivity towards oxidation of the secondary alcohol is achieved when converting vicinal diols such as 1,2-octanediol and 1,2-decanediol. | ||||
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| Language | Wos | 000397584000003 | Publication Date | 2017-01-26 | |
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| ISSN | 1615-4150; 1615-4169 | ISBN | Additional Links | UA library record; WoS full record; WoS citing articles | |
| Impact Factor | 5.646 | Times cited | 4 | Open Access | |
| Notes | ; This work was financially supported by the University of Antwerp (BOF), the Research Foundation – Flanders (FWO) and the Hercules Foundation. ; | Approved | Most recent IF: 5.646 | ||
| Call Number | UA @ admin @ c:irua:139795 | Serial | 5559 | ||
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