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Author de Nolf, W.; Janssens, K.
Title Micro X-ray diffraction and fluorescence tomography for the study of multilayered automotive paints Type A1 Journal article
Year 2010 Publication Surface and interface analysis Abbreviated Journal Surf Interface Anal
Volume 42 Issue 5 Pages 411-418
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Combined microscopic X-ray fluorescence/microscopic X-ray diffraction (µ-XRF/µ-XRD) tomography is a recently developed method that allows the visualization of the distribution of chemical elements and the associated crystalline phases inside complex, heterogeneous materials of extended thickness (millimeter range) in a nondestructive fashion. In this paper, the accuracy and resolution with which the individual layers in a multilayer stack of automotive paints can be distinguished is evaluated, and some of their properties measured. A paint layer system of eight layers was investigated, in which eight different crystalline substances were identified, each layer consisting of an organic, synthetic resin doped with finely milled inorganic compounds that serve as pigments or to strengthen the layer. In the XRD tomograms, all paint layers could be straightforwardly distinguished and their average thickness calculated. In case the filtered back projection method was used for tomogram reconstruction, a spatial resolution comparable to the microbeam size was obtained indicating no significant reconstruction blurring. When a more robust reconstruction method, such as the maximum-likelihood expectation maximization method, was employed, tomograms showing fewer artifacts were obtained, but with a spatial resolution that was two times worse. In the corresponding XRF tomograms, significant self-absorption distorted the element-specific tomograms corresponding to the low-energy (<7 keV) characteristic radiation and limited their usefulness. It can be concluded that microbeam XRD tomography allows the accurate visualization of the distribution of crystalline phases in multilayered automotive paint materials of millimeter dimensions with sufficient resolution to allow separate characterization of each layer in terms of its crystal-phase composition and thickness.
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Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos 000277350900012 Publication Date 2009-11-10
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0142-2421 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 1.132 Times cited 70 Open Access
Notes ; This research was supported by the Interuniversity Attraction Poles Programme-Belgian Science Policy (IUAP VI/16) and funded by beam time grants from HASYLAB. This paper also presents results from a GOA project of the Research Fund of the University of Antwerp (Belgium), and of FWO (Brussels, Belgium) project nos. G.0177.03, G.0103.04, and G.0689.06. We also would like to acknowledge the Institute of Forensic Research in Krakow, Poland, and in particular Dr J. Zieba for providing the paint layer sample. ; Approved Most recent IF: 1.132; 2010 IF: 1.249
Call Number UA @ admin @ c:irua:82764 Serial 5717
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Author Schmid, R.; Wilke, M.; Ober, R.; Dong, S.; Janssens, K.; Falkenberg, G.; Franz, L.; Gaab, A.
Title Micro-XANES determination of ferric iron and its application in thermobarometry Type A1 Journal article
Year 2003 Publication Lithos Abbreviated Journal
Volume 70 Issue Pages 381-392
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos 000186356500017 Publication Date 2003-09-17
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:42916 Serial 5718
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Author Nuyts, G.; Cagno, S.; Bugani, S.; Janssens, K.
Title Micro-XANES study on Mn browning: use of quantitative valence state maps Type A1 Journal article
Year 2015 Publication Journal of analytical atomic spectrometry Abbreviated Journal J Anal Atom Spectrom
Volume 30 Issue 3 Pages 642-650
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Historical glass, especially non-durable medieval glass, can undergo corrosion. This sometimes results in the formation of dark-coloured manganese-rich inclusions that reduce the transparency of the glass. While unaltered bulk glass contains manganese mainly present in the +II valence state, inside the inclusions Mn is present in higher valence states (+III to +IV). Two different strategies may be considered by conservators when aiming to improve the transparency. One is based on the reduction of highly oxidised black/brown compounds using mildly reducing solutions, while the other focuses more on the extraction of manganese from the inclusions by the application of chelating agents. In this paper, a method for quantitative mapping of the Mn speciation inside partially corroded historical windowpanes based on X-Ray Absorption Near-Edge Structure (XANES) spectroscopy is discussed. The calibration of such Mn valence state maps based on the combo method, a fairly reliable way to determine the oxidation state, is described in more detail. This method is used to evaluate the effect of reducing treatments on historical glass, dated to the 14th century and originating from Sidney Sussex College (Cambridge, UK), suffering from Mn browning. Glasses were examined by means of Synchrotron Radiation (SR) based microscopic X-Ray Absorption Near-Edge Structure (mXANES) spectroscopy and microscopic X-Ray Fluorescence (mXRF). X-Ray elemental distribution maps of glass cross-sections are recorded at different energies, while Mn K-edge spectra are used to convert these into Mn valence state (VS) maps. Such valence state maps will allow evaluation of a reducing treatment.
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Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos 000350650800009 Publication Date 2015-02-23
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0267-9477 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 3.379 Times cited 8 Open Access
Notes ; This research was supported by the Interuniversity Attraction Poles Programme Belgian Science Policy (IUAP VI/16) and partially by the Research Council of Norway through its Centres of Excellence funding scheme, project number 223268/ F50. The text also presents results of Center of Excellence AGRECHEM (Research Fund University of Antwerp, Belgium) and from the Fund for Scientific Research (FWO, Brussels, Belgium) projects no. G.0C12.13 and G.01769.09. We gratefully acknowledge ESRF for granting beamtime (experiment EC768) and the beamline scientists of ID21 for their support. The authors also want to thank Leonie Seliger of Canterbury Cathedral, UK, the Sidney Sussex College Council and Bursar Charles Larkum for providing the archaeological samples of the Franciscan Friary which are kept in store for Sidney Sussex College in Cambridge (UK). ; Approved Most recent IF: 3.379; 2015 IF: 3.466
Call Number UA @ admin @ c:irua:125476 Serial 5719
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Author Janssens, K.; Vekemans, B.; Vincze, L.; Adams, F.; Rindby, A.
Title A micro XRF spectrometer based on rotating anode generator and capillary optics Type A1 Journal article
Year 1996 Publication Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal
Volume 51 Issue 13 Pages 1661-1678
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 0038-6987 ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:14256 Serial 5720
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Author Denecke, M.A.; Somogyi, A.; Janssens, K.; Simon, R.; Dardenne, K.; Noseck, U.
Title Microanalysis (micro-XRF, micro-XANES, and micro-XRD) of a tertiary sediment using microfocused synchrotron radiation Type A1 Journal article
Year 2007 Publication Microscopy and microanalysis Abbreviated Journal Microsc Microanal
Volume 13 Issue 3 Pages 165-172
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos 000246814100004 Publication Date 2007-05-09
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1431-9276 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 1.891 Times cited 31 Open Access
Notes Approved Most recent IF: 1.891; 2007 IF: 1.941
Call Number UA @ admin @ c:irua:64739 Serial 5721
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Author Padilla, R.; Schalm, O.; Janssens, K.; Arrazcaeta, R.; van Espen, P.
Title Microanalytical characterization of surface decoration in Majolica pottery Type A1 Journal article
Year 2005 Publication Analytica chimica acta Abbreviated Journal Anal Chim Acta
Volume 535 Issue 1-2 Pages 201-211
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos 000228194200025 Publication Date 2005-01-15
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2670 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 4.95 Times cited 20 Open Access
Notes Approved Most recent IF: 4.95; 2005 IF: 2.760
Call Number UA @ admin @ c:irua:52143 Serial 5722
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Author Terzano, R.; Spagnuolo, M.; Medici, L.; Dorriné, W.; Janssens, K.; Ruggiero, P.
Title Microscopic single particle characterization of zeolites synthesized in a soil polluted by copper or cadmium and treated with coal fly ash Type A1 Journal article
Year 2007 Publication Applied clay science Abbreviated Journal Appl Clay Sci
Volume 35 Issue 1-2 Pages 128-138
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos 000243825800016 Publication Date 2006-09-12
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0169-1317 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 3.101 Times cited 17 Open Access
Notes Approved Most recent IF: 3.101; 2007 IF: 1.861
Call Number UA @ admin @ c:irua:62999 Serial 5723
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Author Janssens, K.; Vincze, L.; Aerts, A.; Vekemans, B.; Adams, F.; Jones, K.; Knöchel, A.
Title Microscopic synchroton radiation induced X-ray fluorescence analysis Type A3 Journal article
Year 1996 Publication Mikrochimica acta: supplementum Abbreviated Journal
Volume Issue 13 Pages 87-115
Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0076-8642 ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:14252 Serial 5724
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Author Janssens, K.H.A.; Adams, F.C.V.; Rindby, A.
Title Microscopic X-ray fluorescence analysis Type MA1 Book as author
Year 2000 Publication Abbreviated Journal
Volume Issue Pages 419 p.
Keywords MA1 Book as author; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN 0-471-97426-9 Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:27576 Serial 5725
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Author Janssens, K.; Vincze, L.; Rubio, J.; Bernasconi, G.; Adams, F.
Title Microscopic X-ray fluorescence analysis Type A1 Journal article
Year 1994 Publication Journal of analytical atomic spectrometry Abbreviated Journal
Volume 9 Issue Pages 151-157
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos A1994NK96200009 Publication Date 2004-04-20
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0267-9477 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:8917 Serial 5726
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Author Janssens, K.; Adams, F.
Title Microscopic X-ray fluorescence analysis at second and third generation synchrotron sources Type A3 Journal article
Year 1997 Publication Debye Institute synchrotron chronicle Abbreviated Journal
Volume Issue 2 Pages 9-14
Keywords A3 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:18303 Serial 5727
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Author Adams, F.; Janssens, K.; Snigirev, A.
Title Microscopical X-ray fluorescence analysis and related methods with laboratory and synchrotron radiation sources Type A1 Journal article
Year 1998 Publication Journal of analytical atomic spectrometry Abbreviated Journal J Anal Atom Spectrom
Volume 13 Issue 5 Pages 319-331
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos 000073808900002 Publication Date 2002-07-26
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0267-9477 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 3.379 Times cited Open Access
Notes Approved Most recent IF: 3.379; 1998 IF: 3.845
Call Number UA @ admin @ c:irua:19322 Serial 5728
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Author Bertrand, L.; Schoeeder, S.; Anglos, D.; Breese, M.B.H.; Janssens, K.; Moini, M.; Simon, A.
Title Mitigation strategies for radiation damage in the analysis of ancient materials Type A1 Journal article
Year 2015 Publication Trends in analytical chemistry Abbreviated Journal Trac-Trend Anal Chem
Volume 66 Issue Pages 128-145
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract The study of materials in cultural heritage artifacts and micro-samples benefits from diagnostic techniques based on intense radiation sources, such as synchrotrons, ion-beam accelerators and lasers. While most of the corresponding techniques are classified as non-destructive, investigation with photons or charged particles entails a number of fundamental processes that may induce changes in materials. These changes depend on irradiation parameters, properties of materials and environmental factors. In some cases, radiation-induced damage may be detected by visual inspection. When it is not, irradiation may still lead to atomic and molecular changes resulting in immediate or delayed alteration and bias of future analyses. Here we review the effects of radiation reported on a variety of cultural heritage materials and describe the usual practice for assessing short-term and long-term effects. This review aims to raise awareness and encourage subsequent research activities to limit radiation side effects.
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Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos 000352248200020 Publication Date 2014-12-22
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0165-9936 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 8.442 Times cited 35 Open Access
Notes ; We wish to acknowledge the support of this initiative by the International Atomic Energy Agency. We gratefully thank Professor Manfred Schreiner of the Institute of Natural Sciences and Technology in the Arts (Akademie den bildenden Kunst, Vienna, Austria) for helpful discussions and insights on this work. We thank all colleagues who accepted to have their work reproduced in this review. IPANEMA at Synchrotron SOLEIL, the Hungarian Academy of Science and IESL-FORTH were supported within the Research Infrastructure program CHARISMA of the 7th Framework Programme of the EU (Grant Agreement no. 228330). MM's contribution is based upon work supported by the National Science Foundation under Grant numbers CHE 1241672 and CHE 1440849. We thank Chris McGlinchey and Lauren Klein (Museum of Modern Art, New York, USA) for their critical rereading of the manuscript. ; Approved Most recent IF: 8.442; 2015 IF: 6.472
Call Number UA @ admin @ c:irua:124627 Serial 5729
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Author Ranjbari, E.; Hadjmohammadi, M.R.; Kiekens, F.; De Wael, K.
Title Mixed hemi/ad-micelle sodium dodecyl sulfate-coated magnetic iron oxide nanoparticles for the efficient removal and trace determination of rhodamine-B and rhodamine-6G Type A1 Journal article
Year 2015 Publication Analytical chemistry Abbreviated Journal Anal Chem
Volume 87 Issue 15 Pages 7894-7901
Keywords A1 Journal article; Pharmacology. Therapy; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Mixed hemi/ad-micelle sodium dodecyl sulfate (SDS)-coated magnetic iron oxide nanoparticles (MHAMS-MIONPs) were used as an efficient adsorbent for both removal and preconcentration of two important carcinogenic xanthine dyes named rhodamine-B (RB) and rhodamine-6G (RG). To gain insight in the configuration of SDS molecules on the surface of MIONPs, zeta potential measurements were performed in different [SDS]/[MIONP] ratios. Zeta potential data indicated that mixed hemi/ad-micelle MHAM was formed in [SDS]/[MIONP] ratios over the range of 1.1 to 7.3. Parameters affecting the adsorption of dyes were optimized as removal efficiency by one variable at-a-time and response surface methodology; the obtained removal efficiencies were ∼100%. Adsorption kinetic and equilibrium studies, under the optimum condition (pH = 2; amount of MIONPs = 87.15 mg; [SDS]/[MIONP] ratio = 2.9), showed that adsorption of both dyes are based on the pseudo-second-order and the Langmuir isotherm models, respectively. The maximum adsorption capacities for RB and RG were 385 and 323 mg g1, respectively. MHAMS-MIONPs were also applied for extraction of RB and RG. Under optimum conditions (pH = 2; amount of damped MHAMS-MIONPs = 90 mg; eluent solvent volume = 2.6 mL of 3% acetic acid in acetonitrile), extraction recoveries for 0.5 mg L1 of RB and RG were 98% and 99%, with preconcentration factors of 327 and 330, respectively. Limit of detection obtained for rhodamine dyes were <0.7 ng mL1. Finally, MHAMS-MIONPs were successfully applied for both removal and trace determination of RB and RG in environmental and wastewater samples.
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Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos 000359277900056 Publication Date 2015-07-08
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 6.32 Times cited 36 Open Access
Notes ; ; Approved Most recent IF: 6.32; 2015 IF: 5.636
Call Number UA @ admin @ c:irua:126583 Serial 5730
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Author Amiri-Aref, M.; Raoof, J.B.; Kiekens, F.; De Wael, K.
Title Mixed hemi/ad-micelles coated magnetic nanoparticles for the entrapment of hemoglobin at the surface of a screen-printed carbon electrode and its direct electrochemistry and electrocatalysis Type A1 Journal article
Year 2015 Publication Biosensors and bioelectronics Abbreviated Journal Biosens Bioelectron
Volume 74 Issue Pages 518-525
Keywords A1 Journal article; Pharmacology. Therapy; Engineering sciences. Technology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract An efficient procedure for the physical entrapment of proteins within a biocompatible matrix and their immobilization on electrode surfaces is of utmost importance in the fabrication of biosensors. In this work, the magnetic entrapment of hemoglobin (Hb) at the surface of a screen-printed carbon electrode (SPCE), through mixed hemi/ad-micelles (MHAM) array of positively charged surfactant supported iron oxide magnetic nanoparticles (Mag-NPs), is reported. The Hb/MHAM@Mag-NPs biocomposite is captured at SPCE by a super magnet (Hb/MHAM@Mag-NPs/SPCE). To gain insight in the configuration of the mixed hemi/ad-micelles of CTAB at Mag-NPs, zeta-potential measurements were performed. The entrapment of Hb at MHAM@Mag-NPs was confirmed by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and Fourier transform infrared spectroscopy (FT-IR). Direct electron transfer of the Hb intercalated into the composite film showed a pair of well-defined quasi-reversible redox peak at formal potential of −0.255 V vs. Ag/AgCl corresponding to heme Fe(III)/Fe(II) redox couple. It shows that the MHAM@Mag-NPs composite could increase the adsorption ability for Hb, thus provides a facile direct electron transfer between the Hb and the substrate. The proposed biosensor showed excellent electrocatalytic activity to the H2O2 reduction in the wide concentration range from 5.0 to 300.0 µM obtained by amperometric measurement. The MichaelisMenten constant (Km) value of Hb at the modified electrode is 55.4 µM, showing its high affinity. Magnetic entrapment offers a promising design for fast, convenient and effective immobilization of protein within a few minutes for determination of the target molecule in low sample volume at disposable cost-effective SPCE.
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Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos 000360772800071 Publication Date 2015-07-05
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0956-5663 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 7.78 Times cited 14 Open Access
Notes ; We are thankful for the BOF financial support from the University of Antwerp and Hercules financial support (SEM). ; Approved Most recent IF: 7.78; 2015 IF: 6.409
Call Number UA @ admin @ c:irua:126535 Serial 5731
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Author Vincze, L.; Vekemans, B.; Janssens, K.; Adams, F.
Title Modeling of photon scattering at high X-ray energies : experiment versus simulation Type A1 Journal article
Year 1999 Publication Journal of analytical atomic spectrometry T2 – 15th International Congress on X-Ray Optics and Microanalysis (ICXOM), AUG 24-27, 1998, ANTWERP, BELGIUM Abbreviated Journal J Anal Atom Spectrom
Volume 14 Issue 3 Pages 529-533
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract The use of a detailed Monte Carlo simulation code for X-ray fluorescence spectrometers is demonstrated for calculating the outcome of X-ray scattering experiments in the incident energy range 40-80 keV. The code was validated by comparisons of experimental and simulated spectral distributions in the case of thick, homogeneous samples in which multiple photon scattering occurs with high probability. The experimental spectral distributions were collected at beamline BW5 of HASYLAB, Germany, where a highly energetic, monochromatic synchrotron beam is available. With respect to heterogeneous samples, the code was employed to evaluate the use of Rayleigh and Compton scatter signals for obtaining three dimensional information on the sample dark matrix composition.
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Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos 000079138500032 Publication Date 2002-07-26
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0267-9477 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 3.379 Times cited Open Access
Notes Approved Most recent IF: 3.379; 1999 IF: 3.677
Call Number UA @ admin @ c:irua:103504 Serial 5732
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Author 't Hart, L.; Storme, P.; Anaf, W.; Nuyts, G.; Vanmeert, F.; Dorriné, W.; Janssens, K.; De Wael, K.; Schalm, O.
Title Monitoring the impact of the indoor air quality on silver cultural heritage objects using passive and continuous corrosion rate assessments Type A1 Journal article
Year 2016 Publication Applied physics A : materials science & processing Abbreviated Journal Appl Phys A-Mater
Volume 122 Issue 10 Pages 923-10
Keywords A1 Journal article; Engineering sciences. Technology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Antwerp Cultural Heritage Sciences (ARCHES)
Abstract There is a long tradition in evaluating industrial atmospheres by measuring the corrosion rate of exposed metal coupons. The heritage community also uses this method, but the interpretation of the corrosion rate often lacks clarity due to the low corrosivity in indoor museum environments. This investigation explores the possibilities and drawbacks of different silver corrosion rate assessments. The corrosion rate is determined by three approaches: (1) chemical characterization of metal coupons using analytical techniques such as electrochemical measurements, SEM-EDX, XRD, and µ-Raman spectroscopy, (2) continuous corrosion monitoring methods based on electrical resistivity loss of a corroding nm-sized metal wire and weight gain of a corroding silver coated quartz crystal, and (3) characterization of the visual degradation of the metal coupons. This study confirms that subtle differences in corrosivity between locations inside a museum can be determined on condition that the same corrosion rate assessment is used. However, the impact of the coupon orientation with respect to the prevailing direction of air circulation can be substantially larger than the impact of the coupon location.
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Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos 000384753800053 Publication Date 2016-09-28
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0947-8396 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 1.455 Times cited 3 Open Access
Notes ; This research has been sponsored by the Belgian Federal Public Planning Service Science Policy (BELSPO) under Project Number BR/132/A6/AIRCHECQ. In this project an innovative monitoring kit is developed that continuously and simultaneously measures both environmental parameters and material behaviour, enabling the study of the cause-effect relationships. The Quanta 250 FEG microscope at the University of Antwerp was funded by the Hercules foundation of the Flemish Government. ; Approved Most recent IF: 1.455
Call Number UA @ admin @ c:irua:135511 Serial 5733
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Author Kempenaers, L.; Janssens, K.; Vincze, L.; Vekemans, B.; Somogyi, A.; Drakopoulos, M.; Simionovici, A.S.; Adams, F.
Title A Monte Carlo model for studying the microheterogeneity of trace elements in reference materials by means of synchrotron microscopic X-ray fluorescence Type A1 Journal article
Year 2002 Publication Analytical chemistry Abbreviated Journal Anal Chem
Volume 74 Issue 19 Pages 5017-5026
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos 000178418100031 Publication Date 2002-09-30
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0003-2700; 5206-882x ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 6.32 Times cited 21 Open Access
Notes Approved Most recent IF: 6.32; 2002 IF: 5.094
Call Number UA @ admin @ c:irua:39871 Serial 5734
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Author Vincze, L.; Janssens, K.; Vekemans, B.; Adams, F.
Title Monte Carlo simulation for X-ray fluorescence spectroscopy Type H3 Book chapter
Year 2004 Publication Abbreviated Journal
Volume Issue Pages 435-461
Keywords H3 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
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Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos Publication Date
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN Additional Links UA library record
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:45380 Serial 5735
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Author Janssens, K.; Vincze, L.; van Espen, P.; Adams, F.
Title Monte Carlo simulation of conventional and synchrotron energy-dispersive X-ray spectrometers Type A1 Journal article
Year 1993 Publication X-ray spectrometry Abbreviated Journal
Volume 22 Issue Pages 234-243
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Chemometrics (Mitac 3)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos A1993LQ04200011 Publication Date 2005-05-28
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0049-8246 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved no
Call Number UA @ admin @ c:irua:6117 Serial 5736
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Author Vincze, L.; Janssens, K.; Vekemans, B.; Adams, F.
Title Monte Carlo simulation of X-ray fluorescence and scattering tomography experiments Type H1 Book chapter
Year 1999 Publication Abbreviated Journal
Volume Issue Pages 328-337
Keywords H1 Book chapter; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos 000083314300033 Publication Date 2003-11-21
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN ISBN 0-8194-3258-x Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor Times cited Open Access
Notes Approved Most recent IF: NA
Call Number UA @ admin @ c:irua:26197 Serial 5737
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Author Vincze, L.; Janssens, K.; Vekemans, B.; Adams, F.
Title Monte Carlo simulation of X-ray fluorescence spectra: part 4: photon scattering at high X-ray energies Type A1 Journal article
Year 1999 Publication Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal Spectrochim Acta B
Volume Issue Pages 1711-1722
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos 000083798600003 Publication Date 2002-07-26
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 0038-6987 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 3.241 Times cited Open Access
Notes Approved Most recent IF: 3.241; 1999 IF: 2.421
Call Number UA @ admin @ c:irua:26354 Serial 5738
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Author Denecke, M.A.; de Nolf, W.; Janssens, K.; Brendebach, B.; Falkenberg, G.; Noseck, U.; Rothkirch, A.
Title mu-X-ray fluorescence and mu-X-ray diffraction investigations of sediment from the Ruprechtov nuclear waste disposal natural analog site Type A1 Journal article
Year 2008 Publication Spectrochimica acta: part B : atomic spectroscopy Abbreviated Journal Spectrochim Acta B
Volume 63 Issue 4 Pages 484-492
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos 000255817200005 Publication Date 2008-01-15
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0584-8547; 0038-6987 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 3.241 Times cited 7 Open Access
Notes Approved Most recent IF: 3.241; 2008 IF: 2.853
Call Number UA @ admin @ c:irua:69131 Serial 5739
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Author Wadsak, M.; Constantinides, I.; Vittiglio, G.; Adriaens, A.; Janssens, K.; Schreiner, M.; Adams, F.C.; Brunella, P.; Wuttmann, M.
Title Multianalytical study of patina formed on archaeological metal objects from Bliesbruck-Reinheim Type A1 Journal article
Year 2000 Publication Microchimica acta Abbreviated Journal Microchim Acta
Volume 133 Issue Pages 159-164
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos 000087797400024 Publication Date 2003-02-12
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0026-3672; 1436-5073 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 4.58 Times cited Open Access
Notes Approved Most recent IF: 4.58; 2000 IF: 1.303
Call Number UA @ admin @ c:irua:28228 Serial 5740
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Author Tilleman, L.; De Henau, S.; Pauwels, M.; Nagy, N.; Pintelon, I.; Braeckman, B.P.; De Wael, K.; Van Doorslaer, S.; Adriaensen, D.; Timmermans, J.-P.; Moens, L.; Dewilde, S.
Title An N-myristoylated globin with a redox-sensing function that regulates the defecation cycle in Caenorhabditis elegans Type A1 Journal article
Year 2012 Publication PLoS ONE Abbreviated Journal Plos One
Volume 7 Issue 12 Pages e48768-9
Keywords A1 Journal article; Engineering sciences. Technology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Globins occur in all kingdoms of life where they fulfill a wide variety of functions. In the past they used to be primarily characterized as oxygen transport/storage proteins, but since the discovery of new members of the globin family like neuroglobin and cytoglobin, more diverse and complex functions have been assigned to this heterogeneous family. Here we propose a function for a membrane-bound globin of C. elegans, GLB-26. This globin was predicted to be myristoylated at its N-terminus, a post-translational modification only recently described in the globin family. In vivo, this globin is found in the membrane of the head mesodermal cell and in the tail stomato-intestinal and anal depressor muscle cells. Since GLB-26 is almost directly oxidized when exposed to oxygen, we postulate a possible function as electron transfer protein. Phenotypical studies show that GLB-26 takes part in regulating the length of the defecation cycle in C. elegans under oxidative stress conditions.
Address
Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos 000313236200008 Publication Date 2012-12-12
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1932-6203 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 2.806 Times cited 6 Open Access
Notes ; SDH is a Ph.D. fellow of the Fund for Scientific Research (FWO). Financial support to SD and LM was provided by the University of Antwerp (BOF UA TOP 2006) and to SD, LM, BPB, by FWO project G.0247.09. The UltraVIEW VoX spinning disk confocal microscope was purchased with support of the Hercules Foundation (Hercules Type 1: AUHA 09/001). The funders had no role in study design, data collection and analysis, decision to publish, or preparation of the manuscript. ; Approved Most recent IF: 2.806; 2012 IF: 3.730
Call Number UA @ admin @ c:irua:102591 Serial 5741
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Author Andrikopoulos, K.S.; Daniilia, S.; Roussel, B.; Janssens, K.
Title In vitro validation of a mobile Raman-XRF micro-analytical instrument's capabilities on the diagnosis of Byzantine icons Type A1 Journal article
Year 2006 Publication Journal of Raman spectroscopy Abbreviated Journal J Raman Spectrosc
Volume 37 Issue 10 Pages 1026-1034
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos 000241209500010 Publication Date 2006-09-20
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0377-0486 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 2.969 Times cited 53 Open Access
Notes Approved Most recent IF: 2.969; 2006 IF: 2.133
Call Number UA @ admin @ c:irua:60709 Serial 5742
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Author Gaetani, C.; Gheno, G.; Borroni, M.; De Wael, K.; Moretto, L.M.; Ugo, P.
Title Nanoelectrode ensemble immunosensing for the electrochemical identification of ovalbumin in works of art Type A1 Journal article
Year 2019 Publication Electrochimica acta Abbreviated Journal Electrochim Acta
Volume 312 Issue 312 Pages 72-79
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract This research is aimed to the study and application of an electrochemical immunosensor for the detection of ovalbumin (OVA) from egg white (or albumen) used as a binder in some works of art, such as some historical photographic prints and tempera paintings. The immunosensor takes advantage of the interesting biodetection capabilities offered by nanoelectrode ensembles (NEEs). The NEEs used to this aim are prepared by template deposition of gold nanoelectrodes within the pores of track-etched polycarbonate (PC) membranes. The affinity of polycarbonate for proteins is exploited to capture OVA from the aqueous extract obtained by incubation in phosphate buffer of a small sample fragment (<1 mg). The captured protein is reacted selectively with anti-OVA antibody, labelled with glucose oxidase (GOx). In the case of positive response, the addition of the GOx substrate (i.e. glucose) and a suitable redox mediator (a ferrocenyl derivative) reflects in the up rise of an electrocatalytic oxidation current, which depends on the OVA amount captured on the NEE, this amount correlating with OVA concentration in the extract. After optimization, the sensor is successfully applied to identify OVA in photographic prints dating back to the late 19th century, as well as in ancient tempera paintings from the 15th and 18th centuries.
Address
Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos 000468595500008 Publication Date 2019-04-29
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0013-4686 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 4.798 Times cited 2 Open Access
Notes ; ; Approved Most recent IF: 4.798
Call Number UA @ admin @ c:irua:159573 Serial 5743
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Author Kukhlevsky, S.V.; Mechler, M.; Csapo, L.; Janssens, K.
Title Near-field diffraction of fs and sub-fs pulses: super resolution of NSOM in space and time Type A1 Journal article
Year 2003 Publication Physics letters : A Abbreviated Journal Phys Lett A
Volume 319 Issue Pages 439-447
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract
Address
Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos 000187351800003 Publication Date 2003-11-07
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0375-9601 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 1.772 Times cited 10 Open Access
Notes Approved Most recent IF: 1.772; 2003 IF: 1.324
Call Number UA @ admin @ c:irua:42959 Serial 5744
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Author Alfeld, M.; Laurenze-Landsberg, C.; Denker, A.; Janssens, K.; Noble, P.
Title Neutron activation autoradiography and scanning macro-XRF of Rembrandt van Rijn's Susanna and the Elders (Gemaldegalerie Berlin) : a comparison of two methods for imaging of historical paintings with elemental contrast Type A1 Journal article
Year 2015 Publication Applied physics A : materials science & processing Abbreviated Journal Appl Phys A-Mater
Volume 119 Issue 3 Pages 795-805
Keywords A1 Journal article; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation)
Abstract Imaging methods with elemental contrast are of great value for the investigation of historical paintings, as they allow for study of sub-surface layers that provide insight into a painting's creation process. Two of the most important methods are neutron activation autoradiography (NAAR) and scanning macro-XRF (MA-XRF). Given the differences between these methods in the fundamental physical phenomena exploited, a theoretical comparison of their capabilities is difficult and until now a critical comparison of their use on the same painting is missing. In this paper, we present a study of Rembrandt van Rijn's painting Susanna and the Elders from the Gemaldegalerie in Berlin employing both techniques. The painting features a considerable number of overpainted features and a wide range of pigments with different elemental tracers, including earth pigments (Mn/Fe), Azurite (Cu), lead white (Pb), vermilion (Hg) and smalt (Co, As). MA-XRF can detect all elements above Si (Z = 14), suffers from few spectral overlaps and can be performed in a few tens of hours in situ, i.e. in a museum. NAAR requires the stay of the painting at a research facility for several weeks, and inter-element interferences can be difficult to resolve. Also, only a limited number of elements contribute to the acquired autoradiographs, most notably Mn, Cu, As, Co, Hg and P. However, NAAR provides a higher lateral resolution and is less hindered by absorption in covering layers, which makes it the only method capable of visualizing P in lower paint layers.
Address
Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos 000354189200001 Publication Date 2015-04-13
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 0947-8396 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 1.455 Times cited 11 Open Access
Notes ; This research was supported by the Interuniversity Attraction Poles Programme-Belgian Science Policy (IUAP VI/16). The text also presents the results of GOA “XANES meets ELNES” (Research Fund University of Antwerp, Belgium) and from FWO (Brussels, Belgium) Project Nos. G.0704.08 and G.01769.09. M. Alfeld received from 2009 to 2013 a PhD fellowship of the Research Foundation-Flanders (FWO). ; Approved Most recent IF: 1.455; 2015 IF: 1.704
Call Number UA @ admin @ c:irua:126034 Serial 5745
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Author Pauwels, D.; Pilehvar, S.; Geboes, B.; Hubin, A.; De Wael, K.; Breugelmans, T.
Title A new multisine-based impedimetric aptasensing platform Type A1 Journal article
Year 2016 Publication Electrochemistry communications Abbreviated Journal Electrochem Commun
Volume 71 Issue Pages 23-27
Keywords A1 Journal article; Engineering sciences. Technology; AXES (Antwerp X-ray Analysis, Electrochemistry and Speciation); Applied Electrochemistry & Catalysis (ELCAT)
Abstract In this work an aptamer-based biosensor is combined with a multisine electrochemical impedance spectroscopy sensing methodology into a novel and promising biosensing strategy. Employing a multisine instead of a traditional single sine measuring method allows the detection and quantification of parameters that provide information about the accuracy and reliability of the results, such as noise and distortions. This does not only lead to a shorter measurement time, but it also enables an easy and fast evaluation of the quality of the data and fitting, leading to more accurate results.
Address
Corporate Author Thesis
Publisher Place of Publication (up) Editor
Language Wos 000383445000006 Publication Date 2016-07-23
Series Editor Series Title Abbreviated Series Title
Series Volume Series Issue Edition
ISSN 1388-2481; 1873-1902 ISBN Additional Links UA library record; WoS full record; WoS citing articles
Impact Factor 4.396 Times cited 1 Open Access
Notes ; ; Approved Most recent IF: 4.396
Call Number UA @ admin @ c:irua:134765 Serial 5746
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